Aioob XML Database Converter and Aioob XML Editor 

With The Free Aioob XML Editor, you can edit XSL, XML, XSD, XSLT and FO documents. The Aioob XML Database converter can convert almost any data source (i.e. Text files, Excel workbooks, Access databases, FoxPro 2.x, ODBC data source e.t.c) into XML.
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Altova Professional XML Suite 

The Altova Professional XML Suite is a comprehensive XML development toolset that delivers tremendous functionality at a special price. It includes Professional Editions of XMLSpy, MapForce, StyleVision, and SchemaAgent, plus the new SemanticWorks.
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Authentic 

Altova Authentic 2005 is a FREE content editor that allows non-technical users to modify content in XML documents and databases. Just fill in electronic forms using the intuitive, word-processor style interface, and your data is instantly updated.
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XMLSpy Home Edition 

Altova XMLSpy 2006 Home Edition is a totally FREE entry level XML development tool for designing and editing XML applications. XMLSpy Home Edition supports Eclipse integration and is ideally suited for hobbyists, entry level developers, and students.
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